VAE emulsion improves adhesion through multiple mechanisms. The ethylene comonomer reduces the glass transition temperature, allowing the emulsion to form flexible films at low temperatures, conforming to irregular surfaces. Hydrogen bonding between VAE’s acetate groups and polar substrates like concrete and wood creates strong primary bonds. For non-porous materials, VAE’s surface wetting properties enable adhesion without primers, unlike some water-based adhesives. Crosslinking during film formation enhances bond durability, with tensile adhesion strength reaching ≥2.0 MPa on concrete. VAE emulsions also exhibit high green strength, maintaining bond integrity during drying. Their ability to bridge micro-cracks in substrates further enhances adhesion longevity, making VAE emulsions the preferred choice for demanding bonding applications in construction and manufacturing.